Chemistry and Physics Faculty Articles

 

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Submissions from 2006

Ion Trajectory Simulations of Axial AC Dipolar Excitation in the Orbitrap, Guangxiang Wu, Robert J. Noll, Wolfgang R. Plass, Qizhi Hu, Richard H. Perry, and R. Graham Cooks

Submissions from 2005

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Measurements of Secondary Organic Aerosol from Oxidation of Cycloalkenes, Terpenes, and m-Xylene Using an Aerodyne Aerosol Mass Spectrometer, Roya Bahreini, Melita D. Keywood, Nga L. Ng, Varuntida Varutbangkul, Song Gao, Richard C. Flagan, John H. Seinfeld, D. R. Worsnop, and J. L. Jimenez

Templated Metal–Organic Frameworks: Synthesis, Structures, Thermal Properties and Solid-State Transformation of Two Novel Calcium–Adipate Frameworks, Daniel T. de Lill, Daniel J. Bozzuto, and Christopher L. Cahill

Poly[(μ3‐n‐hexa­ne‐1,6‐dicarboxyl­ato)dysprosium(III)], Daniel T. de Lill, William W. Brennessel, Lauren A. Borkowski, Noel S. Gunning, and Christopher L. Cahill

Toward Templated Metal−Organic Frameworks:  Synthesis, Structures, Thermal Properties, and Luminescence of Three Novel Lanthanide−Adipate Frameworks, Daniel T. de Lill, Noel S. Gunning, and Christopher L. Cahill

Lanthanide Metallocene Reactivity with Dialkyl Aluminum Chlorides: Modeling Reactions Used to Generate Isoprene Polymerization Catalysts, William J. Evans, Timothy M. Champagne, Dimitri Giarikos, and Joseph W. Ziller

Synthesis and Comparative η1-Alkyl and Sterically Induced Reduction Reactivity of (C5Me5)3Ln Complexes of La, Ce, Pr, Nd, and Sm, William J. Evans, Jeremy M. Perotti, Stosh A. Kozimor, Timothy M. Champagne, Benjamin L. Davis, Gregory W. Nyce, Cy H. Fujimoto, Robert D. Clark, Matthew A. Johnston, and Joseph W. Ziller

Formation of a Bridging Planar Trimethylenemethane Dianion from a Neopentyl Precursor via Sequential β-Alkyl Elimination and C−H Activation, William J. Evans, Jeremy M. Perotti, and Joseph W. Ziller

The Synthetic Utility of [(C5Me5)2Ln][(μ-Ph)2BPh2] in Accessing [(C5Me5)2LnR]x Unsolvated Alkyl Lanthanide Metallocenes, Complexes with High C-H Activation Reactivity, William J. Evans, Jeremy M. Perotti, and Joseph W. Ziller

Trialkylboron/Lanthanide Metallocene Hydride Chemistry: Polydentate Bridging of (HBEt3)- to Lanthanum, William J. Evans, Jeremy M. Perotti, and Joseph W. Ziller

G09: An Edge-on Disk Galaxy Catalog, Stefan Kautsch, E. K. Grebel, F. D. Barazza, and J. S. Gallagher

A14: The Influence of Environment on the Morphological Evolution of Disk-Dominated Galaxies, Stefan Kautsch, E. K. Grebel, and J. S. Gallagher

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Aerosol Properties and Chemical Apportionment of Aerosol Optical Depth at Locations off the U.S. East Coast in July and August 2001, Brian I. Magi, Peter V. Hobbs, Thomas W. Kirchstetter, Tihomir Novakov, Dean A. Hegg, Song Gao, Jens Redemann, and Beat Schmid

Evidence for High Molecular Weight Nitrogen-Containing Organic Salts in Urban Aerosols, Xiaofei Wang, Song Gao, Xin Yang, Hong Chen, Jianmin Chen, Guoshun Zhuang, Jason D. Surratt, Man Nin Chan, and John H. Seinfeld

Submissions from 2004

Chloride Effects in Lanthanide Carboxylate Based Isoprene Polymerization, William J. Evans and Dimitri Giarikos

Utility of Anhydrous Neodymium Nitrate as a Precursor to Extended Organoneodymium Nitrate Networks, William J. Evans, Dimitri Giarikos, Penny S. Workman, and Joseph W. Ziller

Expanding Dinitrogen Reduction Chemistry to Trivalent Lanthanides via the LnZ3/Alkali Metal Reduction System:  Evaluation of the Generality of Forming Ln2(μ-η2:η2-N2) Complexes via LnZ3/K, William J. Evans, David S. Lee, Daniel B. Rego, Jeremy M. Perotti, Stosh A. Kozimor, Ericka K. Moore, and Joseph W. Ziller

Low-Molecular-Weight and Oligomeric Components in Secondary Organic Aerosol from the Ozonolysis of Cycloalkenes and α-Pinene, Song Gao, Melita D. Keywood, Nga L. Ng, Jason D. Surratt, Varuntida Varutbangkul, Roya Bahreini, Richard C. Flagan, and John H. Seinfeld

Particle Phase Acidity and Oligomer Formation in Secondary Organic Aerosol, Song Gao, Nga L. Ng, Melita D. Keywood, Varuntida Varutbangkul, Roya Bahreini, Athanasios Nenes, Jiwen He, Kee Y. Yoo, J. L. Beauchamp, Robert P. Hodyss, Richard C. Flagan, and John H. Seinfeld

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Emissions from Miombo Woodland and Dambo Grassland Savanna Fires, Parikhit Sinha, Peter V. Hobbs, Robert J. Yokelson, Donald R. Blake, Song Gao, and Thomas W. Kirchstetter

Submissions from 2003

Structural Studies of Lanthanide and Yttrium Metallocene Oxides, William J. Evans, Benjamin L. Davis, Gregory W. Nyce, Jeremy M. Perotti, and Joseph W. Ziller

Polymerization of Isoprene by a Single Component Lanthanide Catalyst Precursor, William J. Evans, Dimitri Giarikos, and Nathan T. Allen

Synthesis and Structure of Polymeric Networks of Silver Hexafluoroacetylacetonate Complexes of THF, Toluene, and Vinyltrimethylsilane, William J. Evans, Dimitri Giarikos, Daniel Josell, and Joseph W. Ziller

Synthesis and Reactivity of a Tethered Diene Cyclopentadiene, (C5Me4H)SiMe2(CH2CH=CHCH=CH2), and Its Alkali Metal Salts, William J. Evans, Dimitri Giarikos, and Joseph W. Ziller

Tethered Olefin Studies of Alkene versus Tetraphenylborate Coordination and Lanthanide Olefin Interactions in Metallocenes, William J. Evans, Jeremy M. Perotti, Jason C. Brady, and Joseph W. Ziller

Evaluation of a Silyene Divalent Lanthanide Interaction in the Metallocene Complex, (C5Me5)2Sm[SiNtBuCHCHNtBu], William J. Evans, Jeremy M. Perotti, Joseph W. Ziller, Daniel F. Moser, and Robert West

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Water-Soluble Organic Components in Aerosols Associated with Savanna Fires in Southern Africa: Identification, Evolution, and Distribution, Song Gao, Dean A. Hegg, Peter V. Hobbs, Thomas W. Kirchstetter, Brian I. Magi, and Martin Sadilek

Aerosol Chemistry, and Light-Scattering and Hygroscopicity Budgets during Outflow from East Asia, Song Gao, Dean A. Hegg, and Haflidi Jonsson

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Evolution of Gases and Particles from a Savanna Fire in South Africa, Peter V. Hobbs, Parikhit Sinha, Robert J. Yokelson, Ted J. Christian, Donald R. Blake, Song Gao, Thomas W. Kirchstetter, Tihomir Novakov, and Peter Pilewskie

UV and Optical Spectral Properties in Early-Type Galaxies, Stefan Kautsch and Werner W. Zeilinger

Disorder Characterization of Oxide/Silicon Interfaces from I-V Curves, Louis R. Nemzer and Fredy R. Zypman

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Emissions of Trace Gases and Particles From Savanna Fires in Southern Africa, Parikhit Sinha, Peter V. Hobbs, Robert J. Yokelson, Isaac T. Bertschi, Donald R. Blake, Isobel J. Simpson, Song Gao, Thomas W. Kirchstetter, and Tihomir Novakov

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Distributions of Trace Gases and Aerosols During the Dry Biomass Burning Season in Southern Africa, Parikhit Sinha, Peter V. Hobbs, Robert J. Yokelson, Donald R. Blake, Song Gao, and Thomas W. Kirchstetter

Submissions from 2002

The Bent Metallocene Geometries of Potassium Peralkyl Cyclopentadienyl THF Solvates: Monosolvated [(THF)K(µ-C5Me5)]n, Disolvated [(THF)2K(µ-C5Me5)]n and the Tethered Olefin Complex [(THF)K(μ-C5Me4SiMe2CH2CH=CH2)]n, William J. Evans, Jason C. Brady, Cy H. Fujimoto, Dimitri Giarikos, and Joseph W. Ziller

Direct Synthesis of Heterometallic Europium/Barium Complexes: H2[Eu2Ba6O2(OiPr)16(THF)4] and EuBa2(OC6H4Me-4)7(diglyme)2(DME), William J. Evans, Dimitri Giarikos, Michael A. Greci, and Joseph W. Ziller

Stereoselective Synthesis of Some Novel Heterocyclic Estrone Derivatives by Intramolecular 1,3-Dipolar Cycloaddition, Eva Frank, Janos Wolfling, Beatrix Aukszi, Veronica Konig, Thomas R. Schneider, and Gyula Schneider

Measurements of Selected Dicarboxylic Acids in Marine Cloud Water, Dean A. Hegg, Song Gao, and Haflidi Jonsson

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Characteristics of Active Galactic Nuclei in the Ultraviolet, Stefan Kautsch and Werner W. Zeilinger

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3-Methoxy-1'-phenyl-4'[beta],5-di­hydro-1H-pyrazolo­[4',3':16,17]­estra-1,3,5(10)-triene, Veronica Konig, Thomas R. Schneider, E. Frank, Beatrix Aukszi, Gyula Schneider, and Janos Wolfling

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Clear-Column Radiative Closure During ACE-Asia: Comparison of Multiwavelength Extinction Derived from Particle Size and Composition with Results from Sun Photometry, J. Wang, Richard C. Flagan, John H. Seinfeld, Haflidi Jonsson, D. R. Collins, P. B. Russell, Beat Schmid, Jens Redemann, J. M. Livingston, Song Gao, Dean A. Hegg, and E. J. Welton

Submissions from 2001

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In-cloud oxidation of SO2 by O3 and H2O2: Cloud Chamber Measurements and Modeling of Particle Growth, Peter F. Caffrey, William Hoppel, Glendon Frick, Louise Pasternack, James Fitzgerald, Dean A. Hegg, Song Gao, W. R. Leaitch, Nicole Shantz, Thomas Albrechcinski, and John Ambrusko

Reactivity of the Europium Hexafluoroacetylacetonate (hfac) Complex, Eu(hfac)3(diglyme), and Related Analogs with Potassium: Formation of the Fluoride hfac "ate" Complexes [LnF(hfac)3K(diglyme)]2, William J. Evans, Dimitri Giarikos, Matthew A. Johnston, Michael A. Greci, and Joseph W. Ziller

Reactivity of the Substituted Butadienes, Isoprene and Myrcene, with Decamethylsamarocene, William J. Evans, Dimitri Giarikos, Christopher B. Robledo, Voon S. Leong, and Joseph W. Ziller

Lanthanide Carboxylate Precursors for Diene Polymerization Catalysis:  Syntheses, Structures, and Reactivity with Et2AlCl, William J. Evans, Dimitri Giarikos, and Joseph W. Ziller

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The Tetramethylpiperidinyl-1-Oxide Anion (TMPO-) as a Ligand in Lanthanide Chemistry: Synthesis of the Per(TMPO-) Complex [(ONC5H6Me4)2Sm(μ-ONC5H6Me4)]2, William J. Evans, Jeremy M. Perotti, Robert J. Doedens, and Joseph W. Ziller

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Experimental and Modeling Studies of Secondary Organic Aerosol Formation and Some Applications to the Marine Boundary Layer, Song Gao, Dean A. Hegg, Glendon Frick, Peter F. Caffrey, Louise Pasternack, Chris Cantrell, William Sullivan, John Ambrusko, Thomas Albrechcinski, and Thomas W. Kirchstetter

Laboratory Studies of the Efficiency of Selected Organic Aerosols as CCN, Dean A. Hegg, Song Gao, W. Hoppel, Glendon Frick, Peter F. Caffrey, W. R. Leaitch, N. Shantz, John Ambrusko, and Thomas Albrechcinski

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Particle Formation and Growth From Ozonolysis of α-pinene, William Hoppel, James Fitzgerald, Glendon Frick, Peter F. Caffrey, Louise Pasternack, Dean A. Hegg, Song Gao, W. Richard Leaitch, Nicole Shantz, Chris Cantrell, Thomas Albrechcinski, John Ambrusko, and William Sullivan

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Sulfur Dioxide Uptake and Oxidation in Sea-Salt Aerosol, William Hoppel, Louise Pasternack, Peter F. Caffrey, Glendon Frick, James Fitzgerald, Dean A. Hegg, Song Gao, John Ambrusko, and Thomas Albrechcinski

Submissions from 2000

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Oxidation of [(Cyclic Triamine)(1,5-Cyclooctadiene)Iridium]+ Cations by Hydrogen Peroxide Forms Metallaoxetanes, Thomas C. Flood, Masanori Iimura, Jeremy M. Perotti, Arnold L. Rheingold, and Thomas E. Concolino

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CI Aquilae, M. O. Jesacher, Stefan Kautsch, S. Kimeswenger, M. S. Muhlbacher, W. Saurer, S. Schmeja, and C. K. Scholz

Submissions from 1998

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b→Sγ Constraints on the Minimal Supergravity Model with Large tanβ, Howard Baer, Michal Brhlik, Diego Castano, and Xerxes Tata

Submissions from 1997

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Naturalness Lowers the Upper Bound on the Lightest Higgs boson Mass in Supersymmetry, Greg W. Anderson, Diego Castano, and Antonio Riotto

Complexes of the I,3-Bis(2-Arylimino) Benz (F) Isoindoline Ligand Including the Crystal Structure of the Cu(II)-Acetate Complex, Donald M. Baird, W. P. Maehlmann, Robert D. Bereman, and P. Singh

Intermediates in the Catalytic Dehydrogenative Coupling of Arylgermanes, John E. Bender, Kyle E. Litz, Dimitri Giarikos, Norman J. Wells, Mark M. Banaszak, and Jeff W. Kampf

Submissions from 1996

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Constraints on the Minimal Supergravity Model from Non-Standard Vacua, Howard Baer, Michal Brhlik, and Diego Castano

Ligand Effects on the δ → δ* Band Energies and Intensities in a Series of Diimine Complexes of Dimolybdenum, Donald M. Baird, F. L. Yang, D. J. Kavanaugh, G. Finness, and K. R. Dunbar

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Consequences of Supergravity with Gauged U(1)R Symmetry, Diego Castano, D. Z. Freedman, and C. Manuel

Submissions from 1995

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Challenging Weak-Scale Supersymmetry at Colliders, Greg W. Anderson and Diego Castano

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Measure of Fine Tuning, Greg W. Anderson and Diego Castano

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Naturalness and Superpartner Masses or When to Give Up on Weak Scale Supersymmetry, Greg W. Anderson and Diego Castano

Mechanism of an Oxygen Atom Transfer Reaction Involving an Oxo-bridged Mo(V) Complex, Donald M. Baird, C. Aburri, L. S. Barron, and S. A. Rodriguez

Submissions from 1994

Aspects of Radiative Electroweak Breaking in the Minimal Supersymmetric Extension of the Standard Model, Diego Castano

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Discrete Symmetries and Isosinglet Quarks in Low-Energy Supersymmetry, Diego Castano and Stephan P. Martin

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Renormalization Group Study of the Standard Model and its Extensions: The Minimal Supersymmetric Standard Model, Diego Castano, E. J. Piard, and P. Raymond

Submissions from 1993

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Mass and Mixing-Angle Patterns in the Standard Model and its Minimal Supersymmetric Extension, H. Arason, Diego Castano, E. J. Piard, and P. Ramond

Submissions from 1992

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Renormalization-Group Study of the Standard Model and its Extensions: The Standard Model, H. Arason, Diego Castano, B. Kesthelyi, S. Mikaelian, E. J. Piard, P. Ramond, and B. D. Wright

Submissions from 1991

Top-Quark and Higgs-Boson Mass Bounds from a Numerical Study of Supersymmetric Grand Unified Theories, Haukur Arason, Diego Castano, Bettina Kesthelyi, Samuel Mikaelian, Eric J. Piard, Pierre Ramond, and Brian D. Wright

Trends in δ → δ* Energies and Intensities in Bis(arylimino)isoindoline Complexes of Dimolybdenum, Donald M. Baird and K. Y. Shih

"Metaplectons" and Fractional Statistics, Diego Castano

Oxidative Deamination of Amino Acids by Molecular Oxygen with Pyridoxal Derivatives and Metal Ions as Catalysts, Venkatesh M. Shanbhag and Arthur E. Martell

Mobility of Pesticides and Their Hydrolysis Metabolites in Soil, L. Somasundaram, Joel R. Coats, Kenneth D. Racke, and Venkatesh M. Shanbhag

Submissions from 1990

Dissociation of Solvent Molecules from Mo2O3I2(dtc)2(solv)2 in Solutions of Non-Coordinating Solvents, Donald M. Baird and Samuel Falzone

Preliminary Chelation and Dissolution Effects of Oxalic Acid and Disodium Oxalate on Polymeric 123-Superconductors, C. E. Carraher, H. Zhuang, F. Medina, Donald M. Baird, R. Pennisi, B. D. Landreth, and F. Nounou

Schiff Bases of Pyridoxal 5'-phosphate and 5'-deoxypyridoxal with Phenylglycine Derivatives and Their Metal Complexes, Venkatesh M. Shanbhag and Arthur E. Martell

Submissions from 1989

Oxygen-Atom Transfer Catalyzed by an Oxo-Bridged Molybdenum(V) Compound, Donald M. Baird, S. Falzone, and J. E. Haky

Structural Characterization of bis(arylimino)isoindoline Complexes of Dimolybdenum, Donald M. Baird, K. Y. Shih, J. H. Welch, and Robert D. Bereman

Aerosol Analysis with the Coastal Zone Color Scanner: A Simple Method for Including Multiple Scattering Effects, Howard R. Gordon and Diego Castano

Revrsed Phase High Performance Liquid Chromatographic Analysis of Triphenylphosphine in a Reaction Mixture, Jerome E. Haky, Donald M. Baird, and Samuel Falzone

Submissions from 1988

Comparative Study of the Electronic Structures of N,N'-Diethyldithiocarbamate and Pyrrole-N-Carbodithioate and Their Nickel(II) Complexes, Wayne P. Anderson and Donald M. Baird

Coastal Zone Color Scanner Atmospheric Correction: Influence of El Chichon, Howard R. Gordon and Diego Castano

Submissions from 1987

Synthesis and Reactions of bis(arylimino)isoindoline Complexes of Dimolybdenum, Donald M. Baird, R. Hassan, and W. K. Kim

Establishment of a Regional High School Instrumentation Center at Western Illinois University, Donald M. Baird and Janos Szamosi

Coastal Zone Color Scanner Atmospheric Correction Algorithm: Multiple Scattering Effects, Howard R. Gordon and Diego Castano

Submissions from 1986

Reactions of Dithiocarbamates of Dimolybdenum -- II. Reaction of Molybdenum Acetate with Two Equivalents of Dithiocarbamate, Donald M. Baird and Scott D. Croll

Reactivity of Dithiocarbamates of Dimolybdenum. 3.1 Crystal and Molecular Structure of Oxobis[(diethylcarbamodithioato)(tetrahydrofuran)iodooxomolybdenum(V)], Donald M. Baird, Arnold L. Rheingold, Scott D. Croll, and A. T. DiCenso

Submissions from 1985

A Laboratory Exercise to Introduce Inorganic Biomimetic Compounds, Donald M. Baird

Preparations and Structures of cis-[Mo2(S2CNC4H4)2(O2CCH3)2OPPh3] and [Mo2(S2PEt3)(O2CCH3)3OPEt3](BF4): Two Quadruply Bonded Dimers Involving Dithio Acid Ligands, Donald M. Baird, Phillip E. Fanwick, and Tom Barwick

Submissions from 1984

Monothio- and Monoseleno-Carbamate Complexes, B. Jack McCormick, Robert D. Bereman, and Donald M. Baird

Submissions from 1983

Resonance Induced Properties in Monothiocarbamates Derived from Aromatic Amines: Comparison of the Coordination Chemistry of Indole and Indoline Monothiocarbamates, Robert D. Bereman, Donald M. Baird, Jon Bordner, and Jay R. Dorfman

New Chemical Reactivity in Aromatic Dithiocarbamate and Monothiocarbamate Ligands: Syntheses of Mo2L4·2THF (L = Pyrrole or indole monothiocarbamate or pyrrole dithiocarbamate) and Mo2L4 (L = indoline monothiocarbamate), Robert D. Bereman, Donald M. Baird, and Charles G. Moreland

Coordination Chemistry of New Sulfur-Containing Ligands. 25. Reduction and Deoxygenation of MoO3+(Aq) by Pyrrole-N-Carbodithioate (L) to Yield Eight-Coordinate MoL4: Crystal and Molecular Structure of Tetrakis(Pyrrole-N-Carbodithioato)Molybdenum-Hemi(Methylene Chloride), Robert D. Bereman, Donald M. Baird, Charles T. Vance, John Hutchinson, and Jon Zubieta

Submissions from 1982

Coordination Chemistry of New Sulfur-Containing Ligands. 22. Synthesis and Structure of bis(pyridine)bis(pyrrole-N-carbothioato)nickel(II), Ni(SOCNC4H4)2(C5H5N)2. Evidence for New Resonance Forms in Monothiocarbamates, Robert D. Bereman, Donald M. Baird, Jay R. Dorfman, and Jon Bordner

Submissions from 1981

1,3-Dithiane-2-carbodithioate: Synthesis and Reactivity Patterns, Donald M. Baird and Robert D. Bereman

Coordination Chemistry of New Sulfur Containing Ligands -- 21. Selected Transition Element Complexes of Pyrrole-n-carbothioate: A New Type of Monothiocarbamate Ligand, Robert D. Bereman, Donald M. Baird, and William E. Hatfield