Chemistry and Physics Faculty Articles
Title
Synthesis and Characterization of a Praseodymium–Adipate Framework Templated with 1,2-bis(4-Pyridyl)ethane: Host–Guest Interactions and Structural Survey
Document Type
Article
Publication Date
12-2007
Publication Title
Crystal Growth and Design
ISSN
1528-7483
Volume
7
Issue/No.
12
First Page
2390
Last Page
2393
Abstract
A new templated metal–organic framework has been synthesized and characterized: [Pr2(C6H8O4)3(H2O)2]·(C12H12N2). This structure represents the completion of a series of lanthanide–adipate metal–organic framework materials that have been templated with 4,4′-bipyridine-derived template molecules. Host–guest interactions have been qualitatively analyzed within this system along with previously templated systems. On the basis of these observations, a series of guidelines have been established to predict template occlusion. These guidelines include hard–soft acid–base considerations, hydrophobic–hydrophilic interactions, hydrogen bonding, and geometric considerations. These criteria may aide in the future utilization of templates in the topological control of metal–organic frameworks.
Additional Comments
NSF grant #s: DMR-0348982, DMR-0419754
NSUWorks Citation
de Lill, D. T., & Cahill, C. L. (2007). Synthesis and Characterization of a Praseodymium–Adipate Framework Templated with 1,2-bis(4-Pyridyl)ethane: Host–Guest Interactions and Structural Survey. Crystal Growth and Design, 7, (12), 2390 - 2393. https://doi.org/10.1021/cg700741v. Retrieved from https://nsuworks.nova.edu/cnso_chemphys_facarticles/230
ORCID ID
0000-0003-0891-7246
DOI
10.1021/cg700741v
Comments
©2007 American Chemical Society