Chemistry and Physics Faculty Articles
Title
Structural Studies of Lanthanide and Yttrium Metallocene Oxides
Document Type
Article
Publication Date
7-1-2003
Publication Title
Journal of Organometallic Chemistry
Keywords
Cyclopentadienyl, Metallocene, Oxide, Lanthanides
ISSN
0022-328X
Volume
677
Issue/No.
1-2
First Page
89
Last Page
95
Abstract
Examination of the chemistry of sterically crowded (C5Me4R)3Ln complexes has provided access to a series of [(C5Me4R)2Ln]2(μ-O) complexes: [(C5Me5)2La]2(μ-O), [(C5Me5)2Nd(NC5H4NC4H8)]2(μ-O), [(C5Me4iPr)2Sm]2(μ-O), [(C5Me4Et)2Gd]2(μ-O), and [(C5Me5)2Sm(NC5H5)]2(μ-O). X-ray crystallographic data on these complexes provide information on the effect of metal and cyclopentadienyl ring size on LnO bond distances and Ln=O=Ln angles, which vary between 173 and 180° in these complexes.
NSUWorks Citation
Evans, W. J., Davis, B. L., Nyce, G. W., Perotti, J. M., & Ziller, J. W. (2003). Structural Studies of Lanthanide and Yttrium Metallocene Oxides. Journal of Organometallic Chemistry, 677, (1-2), 89 - 95. https://doi.org/10.1016/S0022-328X(03)00378-4. Retrieved from https://nsuworks.nova.edu/cnso_chemphys_facarticles/98
DOI
10.1016/S0022-328X(03)00378-4
Comments
©2003 Elsevier B.V. All rights reserved.