"Structural Studies of Lanthanide and Yttrium Metallocene Oxides" by William J. Evans, Benjamin L. Davis et al.

Chemistry and Physics Faculty Articles

Title

Structural Studies of Lanthanide and Yttrium Metallocene Oxides

Authors

William J. Evans, University of California, Irvine
Benjamin L. Davis, University of California, Irvine
Gregory W. Nyce, University of California, Irvine
Jeremy M. Perotti, University of California, IrvineFollow
Joseph W. Ziller, University of California, Irvine

Document Type

Article

Publication Date

7-1-2003

Publication Title

Journal of Organometallic Chemistry

Keywords

Cyclopentadienyl, Metallocene, Oxide, Lanthanides

ISSN

0022-328X

Volume

677

Issue/No.

1-2

First Page

Last Page

Abstract

Examination of the chemistry of sterically crowded (C₅Me₄R)₃Ln complexes has provided access to a series of [(C₅Me₄R)₂Ln]₂(μ-O) complexes: [(C₅Me₅)₂La]₂(μ-O), [(C₅Me₅)₂Nd(NC₅H₄NC₄H₈)]₂(μ-O), [(C₅Me₄ⁱPr)₂Sm]₂(μ-O), [(C₅Me₄Et)₂Gd]₂(μ-O), and [(C₅Me₅)₂Sm(NC₅H₅)]₂(μ-O). X-ray crystallographic data on these complexes provide information on the effect of metal and cyclopentadienyl ring size on LnO bond distances and Ln=O=Ln angles, which vary between 173 and 180° in these complexes.

Comments

NSUWorks Citation

Evans, W. J., Davis, B. L., Nyce, G. W., Perotti, J. M., & Ziller, J. W. (2003). Structural Studies of Lanthanide and Yttrium Metallocene Oxides. Journal of Organometallic Chemistry, 677, (1-2), 89 - 95. https://doi.org/10.1016/S0022-328X(03)00378-4. Retrieved from https://nsuworks.nova.edu/cnso_chemphys_facarticles/98

DOI

10.1016/S0022-328X(03)00378-4

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