Oxidation of [(Cyclic Triamine)(1,5-Cyclooctadiene)Iridium]+ Cations by Hydrogen Peroxide Forms Metallaoxetanes

Authors

Thomas C. Flood, University of Southern California, Los Angeles
Masanori Iimura, University of Southern California, Los Angeles
Jeremy M. Perotti, University of Southern California, Los AngelesFollow
Arnold L. Rheingold, , University of Delaware, Newark
Thomas E. Concolino, , University of Delaware, Newark

Document Type

Article

Publication Title

Chemical Communications

ISSN

1359-7345

Publication Date

8-23-2000

Abstract

Iridaoxetane 3 formed by oxidation of 1 with aqueous H₂O₂ is isolated and characterized, providing a rare example of formation of a metallaoxetane by direct oxidation of a metal–alkene complex.

DOI

10.1039/B002079F

Volume

2000

Issue

17

First Page

1681

Last Page

1682

Comments

©The Royal Society of Chemistry 2000

NSUWorks Citation

Flood, T. C., Iimura, M., Perotti, J. M., Rheingold, A. L., & Concolino, T. E. (2000). Oxidation of [(Cyclic Triamine)(1,5-Cyclooctadiene)Iridium]+ Cations by Hydrogen Peroxide Forms Metallaoxetanes. Chemical Communications, 2000, (17), 1681 - 1682. https://doi.org/10.1039/B002079F. Retrieved from https://nsuworks.nova.edu/cnso_chemphys_facarticles/137