Chemistry and Physics Faculty Articles
Title
Utility of Anhydrous Neodymium Nitrate as a Precursor to Extended Organoneodymium Nitrate Networks
Document Type
Article
Publication Date
2004
Publication Title
Inorganic Chemistry
ISSN
0020-1669
Volume
43
Issue/No.
18
First Page
5754
Last Page
5760
Abstract
Hydrated neodymium nitrates can be readily transformed to anhydrous ether solvates which react with cyclopentadienyl reagents to make organometallic nitrate complexes with variable degrees of oligomerization. Heating Nd(NO3)3(H2O)6 in tetrahydrofuran at reflux, removal of solvent, drying at 100 °C under high vacuum, and addition of hot THF generates Nd(NO3)3(THF)3, 1. Using dimethoxyethane, Nd(NO3)3(DME)2, 2, can be obtained similarly. Addition of NaC5Me5 to 1 generates (C5Me5)Nd(NO3)3(THF)Na(THF)x complexes which crystallize as {[(C5Me5)(NO3)2Nd(THF)(μ-NO3)]2Na(THF)4}[Na(THF)6], 3, or [(C5Me5)Nd(THF)(μ-NO3)3Na(THF)2]n, 4, depending on the conditions. The trimetallic Nd2Na unit in 3 forms an extended system in 4 via bridging nitrates. Addition of KC5Me5 and 18-crown-6 to 1 generates another extended complex [(C5Me5)Nd(THF)(NO3)(μ-NO3)2K(18-crown-6)]n, 5, in which an 18-crown-6 ligated potassium links neodymium centers via two bridging nitrates and an agostic interaction between a C5Me5 methyl group and potassium.
NSUWorks Citation
Evans, W. J., Giarikos, D., Workman, P. S., & Ziller, J. W. (2004). Utility of Anhydrous Neodymium Nitrate as a Precursor to Extended Organoneodymium Nitrate Networks. Inorganic Chemistry, 43, (18), 5754 - 5760. https://doi.org/10.1021/ic049187b. Retrieved from https://nsuworks.nova.edu/cnso_chemphys_facarticles/68
DOI
10.1021/ic049187b
Comments
©2004 American Chemical Society