Chemistry and Physics Faculty Articles
Title
Templated Metal–Organic Frameworks: Synthesis, Structures, Thermal Properties and Solid-State Transformation of Two Novel Calcium–Adipate Frameworks
Document Type
Article
Publication Date
5-2005
Publication Title
Dalton Transactions
ISSN
1477-9226
Volume
12
First Page
2111
Last Page
2115
Abstract
Two novel calcium–adipate framework materials have been synthesized hydrothermally. GWMOF-7 ([Ca(C6H8O4)(H2O)2]·(C10H8N2)) and GWMOF-8 ([Ca(C6H8O4)(H2O)2]·(C12H12N2)) both formed three-dimensional structures and were characterized with single-crystal X-ray diffraction, powder X-ray diffraction, IR spectroscopy and elemental analysis. Thermal properties were also studied with thermogravimetric analysis, and show that these structures undergo a solid-state transformation into a denser three-dimensional framework.
Additional Comments
NSF grant #: DMR-0348982
NSUWorks Citation
de Lill, D. T., Bozzuto, D. J., & Cahill, C. L. (2005). Templated Metal–Organic Frameworks: Synthesis, Structures, Thermal Properties and Solid-State Transformation of Two Novel Calcium–Adipate Frameworks. Dalton Transactions, 12, 2111 - 2115. https://doi.org/10.1039/B502512E. Retrieved from https://nsuworks.nova.edu/cnso_chemphys_facarticles/235
ORCID ID
0000-0003-0891-7246
DOI
10.1039/B502512E
Comments
©The Royal Society of Chemistry 2005