Chemistry and Physics Faculty Articles
Hole‐Size Relationships in the Assembly of a Furandicarboxylate‐Based Metallolinker in Praseodymium Coordination Polymers Synthesized under Basic Conditions
ORCID
0000-0003-0891-7246
Document Type
Article
Publication Title
European Journal of Inorganic Chemistry
ISSN
1434-1948
Publication Date
3-2016
Keywords
Furandicarboxylate, Lanthanides, Coordination polymers, Structure elucidation
Abstract
Two new coordination polymers have been synthesized with 2,5‐furandicarboxylic acid upon base modification. The resulting structures are dependent on the base added. When KOH was used as base, potassium was incorporated into the two‐dimensional coordination polymer, acting as a metallolinker to give [Pr2K2(OH)2(C6H2O5)3(H2O)3]·H2O (1). Synthesis with other alkali hydroxides produced a three‐dimensional metal‐organic framework, [Pr8(OH)6(C6H2O5)9(H2O)15]·3H2O (2), and the alkali metal cations were not incorporated into the structure. Hole‐size effects with bite‐angle analyses indicate that metallolinker formation depends on the cation size. The resulting compounds were characterized by single‐crystal X‐ray diffraction, powder X‐ray diffraction, elemental analysis, and thermogravimetric analysis.
DOI
10.1002/ejic.201501350
Volume
2016
Issue
7
First Page
1085
Last Page
1092
Additional Comments
NSF grant #: 0922931
NSUWorks Citation
Einkauf, J. D., Karram, J. P., Greig, N. E., Chan, B. C., & de Lill, D. T. (2016). Hole‐Size Relationships in the Assembly of a Furandicarboxylate‐Based Metallolinker in Praseodymium Coordination Polymers Synthesized under Basic Conditions. European Journal of Inorganic Chemistry, 2016, (7), 1085 - 1092. https://doi.org/10.1002/ejic.201501350. Retrieved from https://nsuworks.nova.edu/cnso_chemphys_facarticles/244
Comments
©2016 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim