Understanding the Origin of Mutations using Ab Initio Molecular Dynamics

Researcher Information

Abstract

Proton transfer within DNA base pairs is a possible origin for mutations which can ultimately lead to cancer. To better understand this potential source of mutations we have modeled this process using Ab Initio molecular dynamics simulations of model systems for DNA base pairs in water. These simulations have provided insight into how often and when proton transfer occurs in these systems while also highlighting the relationship between the likelihood of a proton transfer event and the way the water molecules are coordinated around the model system for DNA. This in turn has allowed for a greater understanding of potential mechanisms that can lead to mutations and the role of nearby water molecules in facilitating or preventing these mechanisms.

Faculty Sponsors

Dr. Brian Van Hoozen

Project Type

Event

Location

Alvin Sherman Library

Start Date

4-6-2022 12:00 PM

End Date

4-7-2022 5:00 PM

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Apr 6th, 12:00 PM Apr 7th, 5:00 PM

Understanding the Origin of Mutations using Ab Initio Molecular Dynamics

Alvin Sherman Library

Proton transfer within DNA base pairs is a possible origin for mutations which can ultimately lead to cancer. To better understand this potential source of mutations we have modeled this process using Ab Initio molecular dynamics simulations of model systems for DNA base pairs in water. These simulations have provided insight into how often and when proton transfer occurs in these systems while also highlighting the relationship between the likelihood of a proton transfer event and the way the water molecules are coordinated around the model system for DNA. This in turn has allowed for a greater understanding of potential mechanisms that can lead to mutations and the role of nearby water molecules in facilitating or preventing these mechanisms.