Marine & Environmental Sciences Faculty Articles

Reconfiguration of π-conjugated superstructures enabled by redox-assisted assembly

Document Type

Article

Publication Date

1-1-2019

Publication Title

Chemical Communications

ISSN

13597345

Volume

55

Issue/No.

39

First Page

5603

Last Page

5606

Abstract

We show that n-doping supramolecular assemblies built from perylene diimide units provides a means to modulate the structure-function properties of these materials. In addition to highlighting the design principles, a combination of spectroscopic and microscopic characterization correlates an increase in the free-exciton bandwidth with the formation of mesoscale hierarchical superstructures.

DOI

10.1039/c9cc01939a

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