Chemistry and Physics Faculty Articles
Title
Nitroaromatic Sensing with a New Lanthanide Coordination Polymer [Er2(C10H4O4S2)3(H2O)6]N Assembled by 2,2′-Bithiophene-5,5′-Dicarboxylate
Document Type
Article
Publication Date
10-7-2017
Publication Title
New Journal of Chemistry
ISSN
1144-0546
Volume
41
Issue/No.
19
First Page
10929
Last Page
10934
Abstract
A new three dimensional lanthanide-containing coordination polymer composed of 2,2′-bithiophene-5,5′-dicarboxylic acid ([Er2(C10H4O4S2)3(H2O)6]n) was solvothermally synthesized and characterized using single crystal X-ray diffraction, PXRD, FTIR, TGA, and luminescence measurements. The emission of this compound dispersed in ethanol is linker based and is quenched upon addition of nitroaromatic species due to a charge transfer from the MOF to the nitroaromatic species. This compound is able to sense a variety of nitroaromatic species, but is particularly sensitive to nitrophenols and nitroaniline.
NSUWorks Citation
Einkauf, J. D., Ortega, R. E., Mathivathanan, L., & de Lill, D. T. (2017). Nitroaromatic Sensing with a New Lanthanide Coordination Polymer [Er2(C10H4O4S2)3(H2O)6]N Assembled by 2,2′-Bithiophene-5,5′-Dicarboxylate. New Journal of Chemistry, 41, (19), 10929 - 10934. https://doi.org/10.1039/c7nj01677h. Retrieved from https://nsuworks.nova.edu/cnso_chemphys_facarticles/251
ORCID ID
0000-0003-0891-7246
DOI
10.1039/c7nj01677h
