Chemistry and Physics Faculty Articles
Title
New Chemical Reactivity in Aromatic Dithiocarbamate and Monothiocarbamate Ligands: Syntheses of Mo2L4·2THF (L = Pyrrole or indole monothiocarbamate or pyrrole dithiocarbamate) and Mo2L4 (L = indoline monothiocarbamate)
Document Type
Article
Publication Date
1983
Publication Title
Polyhedron
ISSN
0277-5387
Volume
2
Issue/No.
1
First Page
59
Last Page
61
Abstract
The reactions between Mo2(C2H3O2)4 and several new dithio- and monothiocarbamates have been studied. The first example of a dimolybdenum compound of a dithiocarbamate with the “molybdenum acetate” structure is reported (Mo2L4·2THF; L = pyrrole dithiocarbamate). In addition, the synthesis of Mo2L′4·2THF (L′ = pyrrole monothiocarbamate, indole monothiocarbamate, indole dithiocarbamate) and Mo2L″4 (L″ = indoline monothiocarbamate) are reported. A discussion of the unique stabilization of the dithiocarbamate bridge by “aromatic” dithio- and monothiocarbamates is presented.
Additional Comments
Copyright © 1983 Published by Elsevier Ltd.
NSUWorks Citation
Bereman, R. D., Baird, D. M., & Moreland, C. G. (1983). New Chemical Reactivity in Aromatic Dithiocarbamate and Monothiocarbamate Ligands: Syntheses of Mo2L4·2THF (L = Pyrrole or indole monothiocarbamate or pyrrole dithiocarbamate) and Mo2L4 (L = indoline monothiocarbamate). Polyhedron, 2, (1), 59 - 61. https://doi.org/10.1016/S0277-5387(00)88033-X. Retrieved from https://nsuworks.nova.edu/cnso_chemphys_facarticles/25
DOI
10.1016/S0277-5387(00)88033-X
Comments
This paper is number 24 in the series, Coordination Chemistry of New Sulfur Containing Ligands. Paper number 23: R.D. Bereman, D. M. Baird, J. Bordner and J. R. Dorfman, Polyhedron, in press.