"New Chemical Reactivity in Aromatic Dithiocarbamate and Monothiocarbam" by Robert D. Bereman, Donald M. Baird et al.
 

Chemistry and Physics Faculty Articles

Title

New Chemical Reactivity in Aromatic Dithiocarbamate and Monothiocarbamate Ligands: Syntheses of Mo2L4·2THF (L = Pyrrole or indole monothiocarbamate or pyrrole dithiocarbamate) and Mo2L4 (L = indoline monothiocarbamate)

Document Type

Article

Publication Date

1983

Publication Title

Polyhedron

ISSN

0277-5387

Volume

2

Issue/No.

1

First Page

59

Last Page

61

Abstract

The reactions between Mo2(C2H3O2)4 and several new dithio- and monothiocarbamates have been studied. The first example of a dimolybdenum compound of a dithiocarbamate with the “molybdenum acetate” structure is reported (Mo2L4·2THF; L = pyrrole dithiocarbamate). In addition, the synthesis of Mo2L′4·2THF (L′ = pyrrole monothiocarbamate, indole monothiocarbamate, indole dithiocarbamate) and Mo2L″4 (L″ = indoline monothiocarbamate) are reported. A discussion of the unique stabilization of the dithiocarbamate bridge by “aromatic” dithio- and monothiocarbamates is presented.

Comments

This paper is number 24 in the series, Coordination Chemistry of New Sulfur Containing Ligands. Paper number 23: R.D. Bereman, D. M. Baird, J. Bordner and J. R. Dorfman, Polyhedron, in press.

Additional Comments

Copyright © 1983 Published by Elsevier Ltd.

DOI

10.1016/S0277-5387(00)88033-X

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