Chemistry and Physics Faculty Articles
Title
Luminescent Lanthanide Coordination Polymers Synthesized via In-Situ Hydrolysis of Dimethyl-3,4-furandicarboxylate
Document Type
Article
Publication Date
5-2015
Publication Title
Journal of Solid State Chemistry
Keywords
Coordination polymers, Lanthanide luminescence, Quantum yield, Crystal structure
ISSN
0022-4596
Volume
225
First Page
402
Last Page
409
Abstract
Dimethyl-3,4-furandicarboxylate undergoes hydrolysis under hydrothermal conditions with lanthanide (Ln) ions to form two-dimensional coordination polymers, [Ln(C6H2O5)(C6H3O5)(H2O)]n (Ln=Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu). The resulting materials exhibit luminescent properties with quantum yields and lifetimes for the Eu(III) and Tb(III) compounds of 1.1±0.3% and 0.387±0.0001 ms, and 3.3±0.8% and 0.769±0.006 ms, respectively. Energy values for the singlet and triplet states were determined for dimethyl-3,4-furandicarboxylate and 3,4-furandicarboxylic acid. Excited state dynamics and structural features are examined to explicate the reported quantum yields. A series of other FDC structures is briefly presented.
Additional Comments
NSF grant #: 0922931
NSUWorks Citation
Greig, N. E., Einkauf, J. D., Clark, J. M., Corcoran, E. J., Karram, J. P., Kent, C. A., Eugene, V. E., Chan, B. C., & de Lill, D. T. (2015). Luminescent Lanthanide Coordination Polymers Synthesized via In-Situ Hydrolysis of Dimethyl-3,4-furandicarboxylate. Journal of Solid State Chemistry, 225, 402 - 409. https://doi.org/10.1016/j.jssc.2015.01.014. Retrieved from https://nsuworks.nova.edu/cnso_chemphys_facarticles/242
ORCID ID
0000-0003-0891-7246
DOI
10.1016/j.jssc.2015.01.014
Comments
©2015 Elsevier Inc. All rights reserved.