Chemistry and Physics Faculty Articles

Title

Structure and Luminescence of a One-Dimensional Uranium Coordination Polymer Assembled Through Benzophenone-4,4′-dicarboxylate

Document Type

Article

Publication Date

8-1-2013

Publication Title

Inorganica Chimica Acta

Keywords

Uranium, Hydrothermal synthesis, Luminescence, Coordination polymer

ISSN

0020-1693

Volume

404

First Page

215

Last Page

218

Abstract

Uranyl nitrate reacts under hydrothermal conditions with benzophenone-4,4′-dicarboxylic acid to produce a one-dimensional coordination polymer constructed through a double-chain motif. Upon excitation of the organic component in the near-UV, sensitized uranyl emission is observed. Thermogravimetric analysis demonstrates that this material is stable until 245 °C.

Comments

©2013 Elsevier B.V. All rights reserved.

Additional Comments

NSF grant #: 0922931

ORCID ID

0000-0003-0891-7246

DOI

10.1016/j.ica.2013.03.006

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Peer Reviewed

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