Chemistry and Physics Faculty Articles
Engineering the Surface Properties of Poly(dimethylsiloxane) Utilizing Aqueous RAFT Photografting of Acrylate/Methacrylate Monomers
ORCID
0000-0002-7836-7262
Document Type
Article
Publication Title
Macromolecules
ISSN
0024-9297
Publication Date
1-23-2018
Abstract
Polymeric surface grafting offers a tunable way to control the interfacial interactions between a material’s surface and its environment. The ability to tailor the surface properties of poly(dimethylsiloxane) elastomer (PDMSe) substrates with functional chemistry, wettability, and roughness can enhance the fields of biofouling, microfluidics, and medical implants. We developed a reversible addition–fragmentation chain transfer (RAFT) polymerization technique to synthesize a host of copolymers composed of acrylamide, acrylic acid, hydroxyethyl methacrylate, and (3-acrylamidopropyl)trimethylammonium chloride with targetable molecular weight from ∼5 to 80 kg/mol and low dispersity of Đ ≤ 1.13. This RAFT strategy was used in conjunction with photografting to chemically engineer the surface of PDMSe with hydrophilic, hydrophobic, and anionic groups. Varying grafting time and copolymer composition allowed for targetable molecular weight, chemical functionality, and water contact angles ranging from 112° to 14°. These new material surfaces will be evaluated for their antifouling and fouling release potential.
DOI
10.1021/acs.macromol.7b02575
Volume
51
Issue
2
First Page
306
Last Page
317
Additional Comments
US Office of Naval Research grant #s: N00014-13-1-0443, N00014-14-1-0445
NSUWorks Citation
Kuliasha, C. A., Fedderwitz, R. L., Calvo, P. R., Sumerlin, B. S., & Brennan, A. B. (2018). Engineering the Surface Properties of Poly(dimethylsiloxane) Utilizing Aqueous RAFT Photografting of Acrylate/Methacrylate Monomers. Macromolecules, 51, (2), 306 - 317. https://doi.org/10.1021/acs.macromol.7b02575. Retrieved from https://nsuworks.nova.edu/cnso_chemphys_facarticles/217
Comments
©2018 American Chemical Society