Chemistry and Physics Faculty Articles
Title
Detecting Reaction Intermediates in Liquids on the Millisecond Time Scale Using Desorption Electrospray Ionization
Document Type
Article
Publication Date
1-3-2011
Publication Title
Angewandte Chemie International Edition
Keywords
Mass spectrometry, Organometallic catalysis, Reaction intermediates, Ruthenium, Transfer hydrogenation
ISSN
1433-7851
Volume
50
Issue/No.
1
First Page
250
Last Page
254
Abstract
Capturing transient species: The bombardment of a surface‐bound RuII complex with charged droplets containing a ligand allows the detection of reaction intermediates (see figure). The reaction investigated is used to synthesize RuII catalysts containing amino alcohol ligands, which facilitate the asymmetric transfer hydrogenation of ketones and imines.
Additional Comments
Air Force Office of Scientific Research grant #: FA 9550‐10‐1‐0235
NSUWorks Citation
Perry, R. H., Splendore, M., Chien, A., Davis, N. K., & Zare, R. N. (2011). Detecting Reaction Intermediates in Liquids on the Millisecond Time Scale Using Desorption Electrospray Ionization. Angewandte Chemie International Edition, 50, (1), 250 - 254. https://doi.org/10.1002/anie.201004861. Retrieved from https://nsuworks.nova.edu/cnso_chemphys_facarticles/188
DOI
10.1002/anie.201004861
Comments
©2011 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim