Chemistry and Physics Faculty Articles

Title

Detecting Reaction Intermediates in Liquids on the Millisecond Time Scale Using Desorption Electrospray Ionization

Document Type

Article

Publication Date

1-3-2011

Publication Title

Angewandte Chemie International Edition

Keywords

Mass spectrometry, Organometallic catalysis, Reaction intermediates, Ruthenium, Transfer hydrogenation

ISSN

1433-7851

Volume

50

Issue/No.

1

First Page

250

Last Page

254

Abstract

Capturing transient species: The bombardment of a surface‐bound RuII complex with charged droplets containing a ligand allows the detection of reaction intermediates (see figure). The reaction investigated is used to synthesize RuII catalysts containing amino alcohol ligands, which facilitate the asymmetric transfer hydrogenation of ketones and imines.

Comments

©2011 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim

Additional Comments

Air Force Office of Scientific Research grant #: FA 9550‐10‐1‐0235

DOI

10.1002/anie.201004861

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Peer Reviewed

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