Chemistry and Physics Faculty Articles
Title
Co(II) Halide Complexes with 2-amino-3-methylpyridinium and 2-amino-5-methylpyridinium: Synthesis, Crystal Structures, and Magnetic Properties
Document Type
Article
Publication Date
7-10-2010
Publication Title
Journal of Coordination Chemistry
Keywords
Co(II), Magnetism, X-ray structure, XY-anisotropy
ISSN
0095-8972
Volume
63
Issue/No.
13
First Page
2223
Last Page
2238
Abstract
Reaction of CoX2 · nH2O with either 2-amino-3-methylpyridine (3-MAP) or 2-amino-5-methylpyridine (5-MAP) in aqueous acid gave complexes, (3-MAPH)2CoX4 or (5-MAPH)2CoX4 (H2O) n [n = 0,1; X = Cl, Br; 3-MAPH = 2-amino-3-methylpyridinium, 5-MAPH = 2-amino-5-methylpyridinium]. The 3-MAPH salts are formed in the triclinic crystal system while the 5-MAPH salts are formed in the monoclinic crystal system. Three of these compounds exhibit weak antiferromagnetic interactions along with varying degrees of single-ion anisotropy, however, 1 shows easy-plane anisotropy and exhibits a mixture of ferromagnetic and antiferromagnetic interactions.
Additional Comments
NSF grant #: IMR-0314773
NSUWorks Citation
Carnevale, D. J., Landee, C. P., Turnbull, M. M., Winn, M., & Xiao, F. (2010). Co(II) Halide Complexes with 2-amino-3-methylpyridinium and 2-amino-5-methylpyridinium: Synthesis, Crystal Structures, and Magnetic Properties. Journal of Coordination Chemistry, 63, (13), 2223 - 2238. https://doi.org/10.1080/00958972.2010.502230. Retrieved from https://nsuworks.nova.edu/cnso_chemphys_facarticles/220
DOI
10.1080/00958972.2010.502230
Comments
©2010 Taylor & Francis