The Tetramethylpiperidinyl-1-Oxide Anion (TMPO-) as a Ligand in Lanthanide Chemistry: Synthesis of the Per(TMPO-) Complex [(ONC5H6Me4)2Sm(μ-ONC5H6Me4)]2

Authors

William J. Evans, University of California, Irvine
Jeremy M. Perotti, University of California, IrvineFollow
Robert J. Doedens, University of California, Irvine
Joseph W. Ziller, University of California, Irvine

Document Type

Article

Publication Title

Chemical Communications

ISSN

1359-7345

Publication Date

10-25-2001

Abstract

(C₅Me₅)₃Sm reacts with the free radical 2,2,6,6-tetramethylpiperidinyl-1-oxy (TMPO) to form (C₅Me₅)₂ and the per nitroxide [(η¹-ONC₅H₆Me₄)₂ Sm(μ-η¹∶η²-ONC₅H ₆Me₄)]₂

DOI

10.1039/B106869P

Volume

2001

Issue

22

First Page

2326

Last Page

2327

Comments

©The Royal Society of Chemistry 2001

NSUWorks Citation

Evans, W. J., Perotti, J. M., Doedens, R. J., & Ziller, J. W. (2001). The Tetramethylpiperidinyl-1-Oxide Anion (TMPO-) as a Ligand in Lanthanide Chemistry: Synthesis of the Per(TMPO-) Complex [(ONC5H6Me4)2Sm(μ-ONC5H6Me4)]2. Chemical Communications, 2001, (22), 2326 - 2327. https://doi.org/10.1039/B106869P. Retrieved from https://nsuworks.nova.edu/cnso_chemphys_facarticles/136