Chemistry and Physics Faculty Articles

Title

Templated Metal–Organic Frameworks: Synthesis, Structures, Thermal Properties and Solid-State Transformation of Two Novel Calcium–Adipate Frameworks

Document Type

Article

Publication Date

5-2005

Publication Title

Dalton Transactions

ISSN

1477-9226

Volume

12

First Page

2111

Last Page

2115

Abstract

Two novel calcium–adipate framework materials have been synthesized hydrothermally. GWMOF-7 ([Ca(C6H8O4)(H2O)2]·(C10H8N2)) and GWMOF-8 ([Ca(C6H8O4)(H2O)2]·(C12H12N2)) both formed three-dimensional structures and were characterized with single-crystal X-ray diffraction, powder X-ray diffraction, IR spectroscopy and elemental analysis. Thermal properties were also studied with thermogravimetric analysis, and show that these structures undergo a solid-state transformation into a denser three-dimensional framework.

Comments

©The Royal Society of Chemistry 2005

Additional Comments

NSF grant #: DMR-0348982

ORCID ID

0000-0003-0891-7246

DOI

10.1039/B502512E

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