Chemistry and Physics Faculty Articles

Title

Trialkylboron/Lanthanide Metallocene Hydride Chemistry: Polydentate Bridging of (HBEt3)- to Lanthanum

Document Type

Article

Publication Date

8-8-2005

Publication Title

Inorganic Chemistry

ISSN

0020-1669

Volume

44

Issue/No.

16

First Page

5820

Last Page

5825

Abstract

The reaction of [(C5Me5)2LaH]x with BEt3 is reported, and the solid-state structures of the lanthanum product (C5Me5)2La[(μ-H)(μ-Et)2BEt], 1, and its THF adduct (C5Me5)2La(THF)[(μ-H)(μ-Et)BEt2], 2, are compared with that of the hydride-bridged “tuckover” complex (C5Me5)2La(μ-H)(μ-η15-CH2C5Me4)La(C5Me5), 3.

Comments

©2005 American Chemical Society

DOI

10.1021/ic0501061

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Peer Reviewed

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