Chemistry and Physics Faculty Articles
Title
Resonance Induced Properties in Monothiocarbamates Derived from Aromatic Amines: Comparison of the Coordination Chemistry of Indole and Indoline Monothiocarbamates
Document Type
Article
Publication Date
1983
Publication Title
Polyhedron
ISSN
0277-5387
Volume
2
Issue/No.
1
First Page
25
Last Page
30
Abstract
The syntheses of two new monothiocarbamate ligands and selected transition element complexes of each are reported. The complexes of indoline-N-carbothioate (intc) prepared are: NiL2·1.5H2O, ZnL2, NiL2·2py, ZnL2·2py. The complexes of indole N-carbothioate (iltc) are: NiL′2, ZnL′2, Cul′. IR spectral results support a bidentate ligand behavior for both new monothiocarbamates except in ZnL2·2py. Comparison of the IR spectral features of bis(indolylcarbamoyl)-disulfide with that of coordinated indole-N-carbothioate allowed an assignment of the C-S and C-O vibrational frequencies. Evidence for differences in major resonance contributions to the electronic structures of each new ligand are presented. The crystal structure of thebis(indolylcarbamoyl)disulphide is also presented and a comparison is made to pyrrole-N-carbothioate, another aromatic amine monothiocarbamate. The disulphide crystallizes in the centrosymmetric monoclinic space group P21/c with a = 15.64(4)Å, b = 5.228(1)Å,c = 19.271(7)Å, β = 97.20(2)°, V = 1564(1)Å3, d(obsd)(calcd) = (1.50)(1.52) for a molecular weight = 356.1 and Z = 4. Diffraction data were collected with a Syntex Pdiffractiometer with CuKα radiation. Least squares refinement resulted in Rf = 7.0% for all 1213 non zero reflections have (I)> 3σ(I).
Additional Comments
Copyright © 1983 Published by Elsevier Ltd.
NSUWorks Citation
Bereman, R. D., Baird, D. M., Bordner, J., & Dorfman, J. R. (1983). Resonance Induced Properties in Monothiocarbamates Derived from Aromatic Amines: Comparison of the Coordination Chemistry of Indole and Indoline Monothiocarbamates. Polyhedron, 2, (1), 25 - 30. https://doi.org/10.1016/S0277-5387(00)88027-4. Retrieved from https://nsuworks.nova.edu/cnso_chemphys_facarticles/26
DOI
10.1016/S0277-5387(00)88027-4
Comments
This paper is number 23 in the series, Coordination Chemistry of New Sulphur Containing Ligands, Paper Number 22. R. D. Bereman, D. M. Baird, J. R. Dorfman and J. Bordner, Inorg. Chem. 1982, 21, 2365.