Chemistry and Physics Faculty Articles

Title

New Chemical Reactivity in Aromatic Dithiocarbamate and Monothiocarbamate Ligands: Syntheses of Mo2L4·2THF (L = Pyrrole or indole monothiocarbamate or pyrrole dithiocarbamate) and Mo2L4 (L = indoline monothiocarbamate)

Document Type

Article

Publication Date

1983

Publication Title

Polyhedron

ISSN

0277-5387

Volume

2

Issue/No.

1

First Page

59

Last Page

61

Abstract

The reactions between Mo2(C2H3O2)4 and several new dithio- and monothiocarbamates have been studied. The first example of a dimolybdenum compound of a dithiocarbamate with the “molybdenum acetate” structure is reported (Mo2L4·2THF; L = pyrrole dithiocarbamate). In addition, the synthesis of Mo2L′4·2THF (L′ = pyrrole monothiocarbamate, indole monothiocarbamate, indole dithiocarbamate) and Mo2L″4 (L″ = indoline monothiocarbamate) are reported. A discussion of the unique stabilization of the dithiocarbamate bridge by “aromatic” dithio- and monothiocarbamates is presented.

Comments

This paper is number 24 in the series, Coordination Chemistry of New Sulfur Containing Ligands. Paper number 23: R.D. Bereman, D. M. Baird, J. Bordner and J. R. Dorfman, Polyhedron, in press.

Additional Comments

Copyright © 1983 Published by Elsevier Ltd.

DOI

10.1016/S0277-5387(00)88033-X

This document is currently not available here.

Peer Reviewed

Find in your library

Share

COinS